In 2013, Liu Libin got the champion of the junior event of volleyball in 2013 National Games of China with Jiang Chuan and Zhang Binglong as the main three wing spikers.

[1] In 2013–2014 Chinese Volleyball League, he made his debut and got the first champion of the senior event.

[2] In order to improve himself, he decided to join a foreign club and chose Tourcoing Lille Métropole Volley-Ball in 2017.

[3] In 2018, Liu joined JT Thunders in 2018–19 V.League Division 1 Men's as the foreign player of AVC with his former clubmate, Thomas Edgar in Season 15/16 in Beijing Baic Motor.

As a young player, Liu Libin participated in 2015 Asian Men's U23 Volleyball Championship as his earliest International tournament.