The eleven-minute 12" mix of "Volume Two", however, opened with another medley which combined excerpts from the 60's and 70's hits mainly from the soul, R&B and folk rock genres: The Temptations' "Papa Was a Rolling Stone", Sly & the Family Stone's "Dance to the Music", The Rubettes' "Sugar Baby Love", The Flower Pot Men's "Let's Go to San Francisco", America's "A Horse with No Name", The Mamas & the Papas' "Monday Monday" and "California Dreamin'", Scott McKenzie's "San Francisco", Barry McGuire's "Eve of Destruction", Smokey Robinson & the Miracles' "Tears of a Clown", The Supremes' "Stop in the Name of Love", Neil Diamond's "Cracklin' Rosie", Manfred Mann's "Do-Wah-Diddy-Diddy", The Toys' "A Lover's Concerto", Four Tops' "Reach Out I'll Be There" and finally, Simon & Garfunkel's "Sound of Silence".

For the creation of the second Stars on 45 full-length release producer Jaap Eggermont, repeated the process from the previous album by dividing the 12" mix of "Volume Two" into two parts.

The soul/R&B/folk rock part of the 12" "More Stars" medley was placed as track two on Side one, with two of the titles, the Motown hits "Tears of a Clown" and "Stop in the Name of Love", reshuffled and moved to the end and thus, musically connecting with the newly recorded "Supremes Medley".

The opening title "Star Wars and Other Hits" (on the US edition renamed "Introductions" and placed as the closing track on Side one and on the UK edition renamed "The Instrumental Medley"), strung together an assortment of instrumental intros to songs from a wide variety of genres, from a well-known movie themes like "Star Wars" and "The Good, the Bad and the Ugly", TV sitcom theme like "M*A*S*H", the main theme from Jeff Wayne's musical version of "The War of the Worlds", the overture from The Who's musical "Tommy", the 60's and 70's hits like The Walker Brothers' "The Sun Ain't Gonna Shine Anymore", The Stylistics' "Can't Give You Anything (But My Love)", Derek and the Dominos' "Layla"(*), Free's "All Right Now", The Pointer Sisters' "Fire" and Gerry Rafferty's "Baker Street", disco hits like Carl Douglas' "Kung-Fu Fighting", Rod Stewart's "Do You Think I'm Sexy", Boney M.'s "Ma Baker"(*) (featuring an uncredited spoken cameo by Dutch-American DJ Adam Curry), Village People's "Y.M.C.A.

", Michael Jackson's "Don't Stop (Till You Get Enough)"(*) and Foxy's "Get Off" right up to Kim Carnes' "Bette Davis' Eyes"(*) which had been a #1 hit in the US and most other parts of the world only a few months earlier.

The B-side was entitled "Stars on Theme", an alternate mix of an instrumental part from the album version of "'45 Stars Get Ready", and expanded with the same extended break that featured on the A-side of "Volume III", including the reference to Foxy's "Get Off".