In addition to providing vocals and lyrics for the band Lamb, Rhodes has released four solo albums: Beloved One, Bloom and One Good Thing and theyesandeye.
[2] Rhodes has collaborated with 808 State, A Guy Called Gerald, Funkstörung, Pale 3, Sugizo, Plump DJs, Sheila Chandra, Eliza Carthy, Art of Noise, and The Cinematic Orchestra on Ma Fleur and the soundtrack to The Crimson Wing: Mystery of the Flamingos.
[7] Rhodes met engineer Andy Barlow through a friend and recorded a demo tape together, forming the band Lamb.
[7] Rhodes started her own record label, Infinite Bloom, at the beginning of 2006, to issue her debut solo album Beloved One, which was shortlisted for the Nationwide Mercury Music Prize the same year.
[10] In February 2006, she performed together with other female folk singers at the Daughters of Albion event,[11] which was broadcast by BBC 4.
[23] Other contributors include Ian Kellet (guitars), Nikolaj Bjerre (drums), Danny Keane (strings) and Tom Moth (harp).
[2] Although Lamb is famous for blending electronica with jazz and elements of drum and bass, Rhodes's solo work is more organic and rooted in folk music.
[24] She combines finely tuned acoustic guitars—the essence of almost every arrangement—with violin, double bass, and rich percussion.
[32] In 2012, Rhodes also contributed an essay to The First Time I Heard The Smiths, part of an ongoing series where musicians/writers tell their stories of first hearing the music of an iconic artist or band.
[38] The same year, she also featured on the soundtrack for the film The Princess and the Warrior, performing the song "Escape (Afraid of No One)".