Encouraged to chance her luck in the professional music business, Diakovska decided to audition for the 2000 debut of the German reality television program Popstars.

She entered the competition with thousands of other women, and the judges, Simone Angel, Rainer Moslener and Mario M. Mendryzcki, were impressed with her performance in Hamburg.

She earned a position in the top thirty finalists and immediately travelled to Majorca, Spain to join her competitors for a workshop there.

With the final five members of the band in place, Popstars continued tracking the development and struggles of the group who left homes to move into a shared flat near Munich.

The release of The Best of No Angels in November of the same year marked the end of the band, with each member going their separate ways in early 2004.

Diakovska publicly came out as lesbian during the fourth season of the Bulgarian reality show VIP Brother.