[5] In 1999, Doucet signed with music promoter Shauna de Cartier, who shortly after formed Six Shooter Records.

Bazil Donovan, Barry Mirochnick, Lloyd Peterson, Christine Fellows, Sky Onosson and Gilles Fournier performed on the record.

Broken was nominated in 2006 for a Juno Award in the Adult Alternative Album of the Year category.

[10] Despite being excited about living in such a musical city, Doucet was homesick and "longed to be back in Canada".

[11] Six Shooter released Blood's Too Rich on January 8, 2008, in Canada, and on June 24, 2008, in the United States.

Blood's Too Rich was listed on "best of 2008" lists, including a mention from the Independent (UK),[14] and a spot on Nick Hornby's 2008 top 10 favourite songs (for Cleveland) in the New York Times[15] Doucet also got the number one spot on a Toronto Star list of "unforgettable recordings, performances, and moments in 2008"[16] and Blood's Too Rich won the 2008 Canadian Folk Music Award for "Contemporary Album of the Year"[17] In 2010, Doucet released his album Steel City Trawler, also credited to Luke Doucet and the White Falcon.

Doucet has appeared as a guest musician on albums by Sarah McLachlan, Chantal Kreviazuk, Oh Susanna,[22][23] Veda Hille, Melissa McClelland, Delerium, John Bottomley, Maren Ord, Captain Tractor, Mae Moore, Major Maker and Lindy Vopnfjörd.

Doucet recorded with Bryan Adams and Kathleen Edwards on a song produced by Colin Cripps in 2009 that had a limited release.

He also toured the United States and Europe with Blue Rodeo in 2011, replacing Greg Keelor when he was ill. Luke Doucet married Melissa McClelland on June 24, 2006.

McClelland and Doucet have since put their respective solo careers on hold, and now record and perform as the musical duo Whitehorse.