She was engaged to a distant cousin, Emmanuel Théodose de La Tour d'Auvergne (1668–1730), son and heir of Godefroy Maurice de La Tour d'Auvergne, Duke of Bouillon (1641–1721).

Emmanuel Théodose's mother was Marie Anne Mancini, niece of Cardinal Mazarin.

As heir to the Duchy of Bouillon, her husband was styled prince de Turenne.

The couple were married on 1 February 1696 in the chapel of the Hôtel de Crequi, Paris, the town house of her maternal grandfather.

Her husband went on to marry three more times; firstly in 1719 to Louise Françoise Angélique Le Tellier (died 1719) a grand daughter of Louvois; again in 1720 to Anne Marie Christiane de Simiane (died 1722) and again in 1725 to Louise Henriette Françoise de Lorraine.