Mastura graduated with a Bachelor of Laws in Honors from the University of Kent, United Kingdom in 1984.

[1] Mastura is a Member of the UMNO Women's Committee of the Telok Kemang Division, Negeri Sembilan.

In addition, Mastura is also active as a member of the Perak State Charity and Welfare Agency (BAIDURI).

[5] In 2022 general election, she was dropped by the party to contest and instead nominate caretaker Member of the Perak State Legislative Assembly (MLA) for Bukit Chandan Maslin Sham Razman for the Kuala Kangsar federal seat.

[8] Her eldest son, Wan Emir Astar was married with Malaysian actress and TV presenter, Mira Filzah.