She was a key member of the 2006–2007 Scarlet Knights women's basketball team that reached the NCAA Championship game.

Source[3] Ajavon played for the USA team in the 2007 Pan American Games in Rio de Janeiro, Brazil.

[4] Ajavon played primarily off the bench during her rookie WNBA season, but averaged 8.0 points per game.

[5] In her first season with Washington, Ajavon put up remarkably similar numbers to her first WNBA campaign.

Ajavon helped the Mystics reach the playoffs, where she played well, scoring 19 points in just 34 total minutes, but Washington suffered a two-game sweep at the hands of the Indiana Fever.