In October 1998, Prime Minister Janez Drnovšek became the first Slovene head of state to visit Mexico.

Both sides underlined that the session of the Mixed Commission presented a good opportunity for the establishment of foundations for mutual relations in the fields of education, science, culture and sport, as well as for reflection on the role of international co-operation as a factor for social change and as an essential means for the realization of global and sustainable development of countries.

[2] In May 2006, Mexican President Vicente Fox met with Slovene Prime Minister Janez Janša in Vienna, where both leaders were attending the IV Latin America, the Caribbean and the European Union Summit.

[3] High-level visits from Mexico to Slovenia[2] High-level visits from Slovenia to Mexico[2] Both nations have signed a few bilateral agreements such as an Agreement on Educational and Cultural Cooperation (1996) and a Memorandum of Understanding for the Establishment of a Mechanism of Consultation in Matters of Mutual Interest (1996).

Slovenia's main exports to Mexico include: automobile and machinery parts and computer wires.