The song was produced by American rock musician Jack White, who discovered the composition when he was visiting Lynn at her home.

[3] Writer Stephen Deusner commented that "Miss Being Mrs." was also "about sex, about love, about security, and ultimately about the realization that all of that is gone–nothing but a memory at this point in her life.

Rock musician Jack White discovered the song a pile of old handwritten lyrics in Lynn's house.

"It’s her self-penned 'Miss Being Mrs.', a tune that typifies Lynn’s genius – an ability to speak to her own situation, and to those of her audience at the same time.

Writers commented that the song had "a closer connection to Lynn’s heart, as it was released as a tribute to her late husband.

[9] Despite its critical success, "Miss Being Mrs." did not place on any Billboard surveys, including the Hot Country Songs chart.

The single was promoted at the Academy of Country Music Awards around the same time when Lynn performed the track alongside Vince Gill on acoustic guitar.