The college caters for years 12-13, where students can gain A-Level and AS-Level qualifications, with results above the national standards.

The Moorlands VIth form campus is located adjacent to Painsley Academy and students from the VIth form can use the Cheadle Schools sports hall facility based on the Cheadle High School Academy.

Moorside High school is located furthest away from the sixth form, in the town of Werrington, on the borders of Stoke-On-Trent and provides a small number of teaching staff to the college.

The Moorlands Sixth Form teaches physics, chemistry, biology, mathematics, English language and literature, German, French, Spanish, philosophy, religion and ethics, computing, geography, history, art, textiles, product design, beliefs and values, business studies, economics, performing arts, health and social care, sociology, psychology, vocational business, media studies, advanced mathematics, physical education, music, and drama.

Moorlands Sixth Form College consistently gains some of the top A-Level results in Stoke-On-Trent, Staffordshire and the Midlands.