Golden Smog was a loosely connected group of musicians comprising, at various times, members of Soul Asylum, The Replacements, Wilco, The Jayhawks, Run Westy Run, The Honeydogs and Big Star.

Golden Smog's lineup has often changed, but relative constants who appear on all the recordings are guitarists Kraig Johnson (Run Westy Run), Dan Murphy (Soul Asylum) and Gary Louris (The Jayhawks), along with bassist Marc Perlman (The Jayhawks).

The album sleeve art was by the band's then-drummer, Chris Mars.

Writing for Allmusic, music critic Jason Ankeny wrote of the album "After a few years of haphazard shows in and about their native Minneapolis, the members of Golden Smog were approached by a small local label to put out a record; many, many beers later, On Golden Smog appeared.

"[2] The band members of Golden Smog used pseudonyms in the credits.