The DVD features their concert at Windsor Racecourse in London, United Kingdom, as part of the Vodafone TBA secret gigs.

Most of the songs on Live from London originate from their debut album PCD, but it also contains an interlude titled "Show Me What You Got", which was written by Nicole Scherzinger and Polow da Don where they engage in a sing-song dance game whilst individually introducing themselves and their talents at hand.

[1] People magazine contributors Chuck Arnold and Ivory Jeff Clinton wrote that the Pussycat Dolls "[push] all the right buttons" and described the live performance as "fun" and "frivolous.

"[3] In the United States, PCD Live from London debuted and peaked at number 12 on the Music Video Sales chart on December 23, 2006.

[4] On the ARIA Top 40 Music DVDs chart in Australia, the DVD debuted at number 13 on the week commencing December 11, 2006.