This is a list of the Permanent Representatives of Ukraine to the United Nations.

On 26 June 1945, the Charter of the United Nations was signed and came into force on 24 October 1945.

Ukraine was among the first countries that signed the United Nations Charter, becoming a founding member of the United Nations among 51 countries.

Dmitry Manuilsky, head of the Ukrainian delegation at the United Nations Conference on International Organization, held in April–June 1945 in San Francisco, was elected Chairman of the First Committee, which elaborated the Preamble and Chapter 1 (Purposes and Principles) of the United Nations Charter.

The permanent mission also includes about 10 various secretaries and attaches.