In 1725, she was placed on the list of 99 princesses regarded as suitable for marriage with Louis XV of France (which would require that she convert to Catholicism), but she was removed from the list because Denmark-Norway was an arch enemy toward Sweden, the traditional ally of France, and that such a marriage could potentially disturb the French-Swedish alliance.

[1] In the early 1730s, her brother the king tried to arrange a marriage between her and Frederick, Prince of Wales, but the negotiations did not succeed and she remained unmarried.

This meant that she continued to spend much of her time at court, when the queen dowager attended it: Juliana Maria became de facto regent in 1772.

[4] In her will from 1773, Charlotte Amalie created a foundation, Prinsesse C.A.s stiftelse, to finance the upbringing of poor girls of all classes.

The main building owes its current appearance ton adaption undertaken by Frederick VIII of Denmark in the 1850s.