Nitrocellulose

[4][5] The chemical equation for the formation of the trinitrate is The yields are about 85%, with losses attributed to complete oxidation of the cellulose to oxalic acid.

[6] In terms of lacquers and coatings, nitrocellulose dissolves readily in organic solvents, which upon evaporation leave a colorless, transparent, flexible film.

[6] For space flight, nitrocellulose was used by Copenhagen Suborbitals on several missions as a means of jettisoning components of the rocket/space capsule and deploying recovery systems.

[12][13][citation needed] In 1832 Henri Braconnot discovered that nitric acid, when combined with starch or wood fibers, would produce a lightweight combustible explosive material, which he named xyloïdine.

[20] A few years later in 1838, another French chemist, Théophile-Jules Pelouze (teacher of Ascanio Sobrero and Alfred Nobel), treated paper and cardboard in the same way.

By coincidence, a third chemist, the Brunswick professor F. J. Otto had also produced guncotton in 1846 and was the first to publish the process, much to the disappointment of Schönbein and Böttger.

[26] Guncotton containing more than 13% nitrogen (sometimes called insoluble nitrocellulose) was prepared by prolonged exposure to hot, concentrated acids[26] for limited use as a blasting explosive or for warheads of underwater weapons such as naval mines and torpedoes.

[27] Safe and sustained production of guncotton began at the Waltham Abbey Royal Gunpowder Mills in the 1860s, and the material rapidly became the dominant explosive, becoming the standard for military warheads, although it remained too potent to be used as a propellant.

More-stable and slower-burning collodion mixtures were eventually prepared using less concentrated acids at lower temperatures for smokeless powder in firearms.

The first practical smokeless powder made from nitrocellulose, for firearms and artillery ammunition, was invented by French chemist Paul Vieille in 1884.

As a projectile driver, it had around six times the gas generation of an equal volume of black powder and produced less smoke and less heating.

"[28] In combination with breech-loading artillery, such high explosive shells could cause greater damage than previous solid cannonballs.

During the first World War, British authorities were slow to introduce grenades, with soldiers at the front improvising by filling ration tin cans with gun cotton, scrap and a basic fuse.

Unwashed nitrocellulose (sometimes called pyrocellulose) may spontaneously ignite and explode at room temperature, as the evaporation of water results in the concentration of unreacted acid.

[27] In 1855, the first human-made plastic, nitrocellulose (branded Parkesine, patented in 1862), was created by Alexander Parkes from cellulose treated with nitric acid and a solvent.

[32] Projector fires and spontaneous combustion of nitrate footage stored in studio vaults and in other structures were often blamed during the early to mid 20th century for destroying or heavily damaging cinemas, inflicting many serious injuries and deaths, and for reducing to ashes the master negatives and original prints of tens of thousands of screen titles,[33] turning many of them into lost films.

Even when nitrate stock did not start the blaze, flames from other sources spread to large nearby film collections, producing intense and highly destructive fires.

[35][36] Yet again, on June 13 in Philadelphia, a fire and a series of explosions ignited inside the 186-square-meter (2,000-square-foot) film vault of the Lubin Manufacturing Company and quickly wiped out virtually all of that studio's pre-1914 catalogue.

The use of volatile nitrocellulose film for motion pictures led many cinemas to fireproof their projection rooms with wall coverings made of asbestos.

Unlike most other flammable materials, nitrocellulose does not need a source of air to continue burning, since it contains sufficient oxygen within its molecular structure to sustain a flame.

Today, nitrate film projection is rare and normally highly regulated and requires extensive precautions, including extra health-and-safety training for projectionists.

Today, the Dryden Theatre at the George Eastman Museum is one of a few theaters in the world that is capable of safely projecting nitrate films and regularly screens them to the public.

[8] In 1929, several tons of stored X-ray film were ignited by steam from a broken heating pipe at the Cleveland Clinic in Ohio.

That tragedy claimed 123 lives during the fire and additional fatalities several days later, when hospitalized victims died due to inhaling excessive amounts of smoke from the burning film, which was laced with toxic gases such as sulfur dioxide and hydrogen cyanide.

Nitrocellulose was found to gradually decompose, releasing nitric acid and further catalyzing the decomposition (eventually into a flammable powder).

[54] Frank Hastings Griffin invented the double-godet, a special stretch-spinning process that changed artificial silk to rayon, rendering it usable in many industrial products such as tire cords and clothing.

Most automobile "touch up" paints are still made from lacquer because of its fast drying, easy application, and superior adhesion properties – regardless of the material used for the original finish.

It fell out of favor for mass production use for a number of reasons including environmental regulation and the cost of application vs. polyurethane finishes.

The nitrocellulose lacquer yellows and cracks over time, and custom shops will reproduce this aging to make instruments appear vintage.

The invention enjoyed a brief popularity, but the Hyatt balls were extremely flammable, and sometimes portions of the outer shell would explode upon impact.

Cosmetic pads made of nitrocellulose
NFPA 704 four-colored diamond Health 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g. chloroform Flammability 3: Liquids and solids that can be ignited under almost all ambient temperature conditions. Flash point between 23 and 38 °C (73 and 100 °F). E.g. gasoline Instability 3: Capable of detonation or explosive decomposition but requires a strong initiating source, must be heated under confinement before initiation, reacts explosively with water, or will detonate if severely shocked. E.g. hydrogen peroxide Special hazards (white): no code
Table tennis ball, prepared from nitrocellulose (Celluloid)
Pure nitrocellulose
Workman operating a guncotton press behind a protective rope screen, 1909
Deflagration test of nitrocellulose in slow motion
Jam tin grenades were made in World War I using gun cotton
Nitrocellulose film on a light box, showing deterioration, from Library and Archives Canada collection
Lubin film vault custodian Stanley Lowry (foreground) surveys the rubble after fire and explosions, June 1914.
Decayed nitrate film, EYE Film Institute Netherlands
'United States Inter-Agency Committee for Nitrate Film Vault Tests' – film transfer from 1948 about testing storage and flame suppression methods of nitrate film stock; runtime 00:08:41