[6] Radivoje and his siblings gained their elementary education from a teacher their father brought to the village from Bela Crkva.

He was elected president of the Association in 1851, shortly before the group was banned because of its criticism of the Defenders of the Constitution.

Milojković left his position in September 1855, when he was awarded state scholarship and went on to study law at Heidelberg University for three years.

After graduating in 1858, Milojković was granted a scholarship for an additional year during which he fulfilled his dream of visiting Paris with a friend from the university.

While in France, he met with the philosopher Étienne Vacherot and attended lectures which he personally found interesting.

[8] As president of the Appellate Court, Milojković was given the task of writing a new constitution by Prince Mihailo in June 1867.

He served in the cabinet of Đorđe Cenić for one year, after which he also assumed the title of Prime Minister, a post he would hold until the end of the regency in 1872.

[10] Milojković would successfully manipulate the State Council headed by Jovan Marinović to accept the new constitution in June 1869 with an ultimatum.

[2] During the government of Jovan Marinović, Milojković was chosen as Vice President of the State Council in late 1873.

Two other liberals were also made council members, as Marinović wished for his government to present a non-partisan politics.

[1] In the aftermath of Ilka's assassination attempt in 1882, and taking into account Milojković's experience with police work, King Milan proposed that Milojković lead a new government, with the caveat that the Progressives Milutin Garašanin and Čedomilj Mijatović serve as interior and foreign ministers respectively, and that the Liberals accept Milan's preferred pro-Austrian foreign policy.