[1] She was named to the All-ACC Second Team her sophomore year[2] Williams was named to the pre-season Wooden watch list, a list of players under consideration for the John R. Wooden Award, which will be presented to the outstanding player of the year at the end of the season.

On September 8, 2013, Williams had the best offensive performance in WNBA history as she set the record for most points in a single game by scoring 51 points (which has since been broken by Liz Cambage in July, 2018), at the same time tying the WNBA record for most three-point field goals in a single game, with 8 three-pointers (which has since been broken by Kristi Toliver), in a 98–65 win over the San Antonio Silver Stars.

[8] In the 2015 season, Williams came back healthy and continued to flourish as a player, tying her career-high in scoring average and was voted as a WNBA all-star for the first time in her career.

With Skylar Diggins out with a torn ACL after the first 9 games, Williams stepped in as the starting point guard, leading the Shock to a playoff berth with an 18–16 record which was enough for the number 3 seed in the Western Conference.

[9] Without Williams on the roster, the Sparks would still go on to win the 2016 WNBA Championship after defeating the Minnesota Lynx 3–2 in Finals.

Williams would make her return from injury in Game 2 of the semi-finals against the Mercury, recording 1 rebound in 5 minutes of play.

The Sparks would advance to the Finals for the second season in a row after defeating the Mercury in a 3-game sweep, setting up a rematch with the Lynx.

On June 24, 2018, Williams scored a season-high 25 points off the bench, along with 7 three-pointers in an 80–54 victory over the New York Liberty.

The Sparks finished 15–7 as the number 3 seed with a bye to the second round elimination game but would once again lose to the Connecticut Sun.

According to the arrest report, Williams repeatedly struck Alkeria Davis in the head and pulled her hair after she forced her way into the home.

Authorities said Williams grabbed a firearm, placed it on the trunk and pointed it at one man, saying "you'll get all 18" before speeding off, after the fight was broken up.

In response to the arrest, The Aces issued a statement saying that she is “...precluded from participating in team activities.