Rudolf of Zähringen (also Rudolph, Ralph or Raoul) (c. 1135 – 5 August 1191) was the archbishop of Mainz from 1160 to 1161 and prince-bishop of Liège.

After the death of Arnold of Selenhofen, the citizens of Mainz elected him archbishop, but the city had been placed under the interdict and the aristocracy and clergy had fled to Frankfurt am Main, where they elected Christian of Buch instead.

At the Synod of Lodi, both archbishops-elect were deposed and Rudolf was excommunicated.

In 1167, already released from his excommunication, he became bishop of Liège, a position almost as secularly important as that of Mainz.

As bishop, he supported his brother, Berthold IV, Duke of Zähringen.