She grew up in both Ghana and Russia with her 4 siblings and is the younger sister of Eric Don-Arthur, the 2016 National Democratic Congress Parliamentary Candidate for the Effutu Constituency.

Later, she left to the United Kingdom to study at the West London College and in 2011 proceeded to Mink Cosmetics where she graduated with a certificate in makeup artistry, hair styling and special effects.

[7] Don-Arthur has worked on a number of celebrities in both the Ghanaian and Nigerian entertainment industry such as Omotola Jalade Ekehinde, Efya, Joselyn Dumas, Juliet Ibrahim, Nadia Buari, Jackie Appiah, Jim Iyke, Yvonne Okoro and DJ Cuppy.

[10] She has created makeup editorials for magazines Glitz Africa, Debonair Afrik, Dream Wedding, and Haute Canoe working alongside Ghanaian photographer Gilbert Asante on these sets.

[13] She was selected as the only Ghanaian makeup artist and West African representative to take part in the New York Fashion Week[14] and worked with Victoria's Secret model, Mayowa Nicholas, Sabah Koj during the Fall/Winter shows.

[17] A number of Ghanaian political figures have also been touched by Alexandrina's expert hands, including Former First Lady of Ghana, Nana Konadu Agyeman-Rawlings, Ursula Owusu, Nana Oye Lithur, Ghana's first Female Chief of Staff,[18] Frema Osei Opare and Foreign Affairs minister, Shirley Ayorkor Botchway.