[1] Golpe began her journalistic career interning at the office of the local newspaper Diario de Cádiz based in Puerto Real while doing her studies.
[4][5] Golpe went on to work at Cadena COPE as an editor, producer and reporter during the weekends in 1998,[1] and she also began doing advertising publicity voice-overs for a range of companies as well as presenting musical and news programmes on the local television broadcaster Canal 7 [es] because she need to earn more money so she could pay for the expenses for her residence.
[4][6] To celebrate the fifth anniversary of CNN+'s launch, Golpe presented the Globalización XXI programme talking about the environment, global initiatives and sustainability.
[1] Golpe was asked to present the Antena 3 Noticias Fin de Semana weekend bulletin alongside Álvaro Zancajo [es] starting from September 2012.
[5][9] Golpe joined the newspaper La Razón as a columnist in May 2016 and contributes to the Más de uno [es] radio programme broadcast by Onda Cero.
[13] In October 2020, Golpe revealed that she had been sexually assaulted and held at knifepoint at her neck by an unknown man in an elevator two decades earlier, in 2000.