Sapphire is a precious gemstone, a variety of the mineral corundum, consisting of aluminium oxide (α-Al2O3) with trace amounts of elements such as iron, titanium, cobalt, lead, chromium, vanadium, magnesium, boron, and silicon.
Because of the remarkable hardness of sapphires – 9 on the Mohs scale (the third-hardest mineral, after diamond at 10 and moissanite at 9.5) – sapphires are also used in some non-ornamental applications, such as infrared optical components, high-durability windows, wristwatch crystals and movement bearings, and very thin electronic wafers, which are used as the insulating substrates of special-purpose solid-state electronics such as integrated circuits and GaN-based blue LEDs.
Significant sapphire deposits are found in Australia, Afghanistan, Cambodia, Cameroon, China (Shandong), Colombia, Ethiopia, India Jammu and Kashmir (Padder, Kishtwar), Kenya, Laos, Madagascar, Malawi, Mozambique, Myanmar (Burma), Nigeria, Rwanda, Sri Lanka, Tanzania, Thailand, United States (Montana) and Vietnam.
For sapphire, Jammu and Kashmir receives the highest premium, although Burma, Sri Lanka, and Madagascar also produce large quantities of fine quality gems.
For most gems of one carat or more, an independent report from a respected laboratory such as GIA, Lotus Gemology, or SSEF, is often required by buyers before they will make a purchase.
In the United States, a minimum color saturation must be met to be called a ruby, otherwise the stone is referred to as a pink sapphire.
The inclusions can alternatively produce a cat's eye effect if the girdle plane of the cabochon is oriented parallel to the crystal's c-axis rather than perpendicular to it.
[5]: 348–350 On 28 July 2021, the world's largest cluster of star sapphires, weighing 510 kg (1,120 lb), was unearthed from Ratnapura, Sri Lanka.
A rarer type, which comes from the Mogok area of Myanmar, features a vanadium chromophore, the same as is present in Verneuil synthetic color-change sapphire.
While at least 1% chromium must be present in corundum before the deep red ruby color is seen, sapphire blue is apparent with the presence of only 0.01% of titanium and iron.
Commercial mining locations for sapphire and ruby include (but are not limited to) the following countries: Afghanistan, Australia, Myanmar/Burma, Cambodia, China, Colombia, India, Kenya, Laos, Madagascar, Malawi, Nepal, Nigeria, Pakistan, Sri Lanka, Tajikistan, Tanzania, Thailand, United States, and Vietnam.
[35] The sapphire deposits of Kashmir are well known in the gem industry, although their peak production took place in a relatively short period at the end of the nineteenth and early twentieth centuries.
Kashmir-origin contributes meaningfully to the value of a sapphire, and most corundum of Kashmir origin can be readily identified by its characteristic silky appearance and exceptional hue.
[41] Un-heated natural stones are somewhat rare and will often be sold accompanied by a certificate from an independent gemological laboratory attesting to "no evidence of heat treatment".
Yogo sapphires do not need heat treating because their cornflower blue color is attractive out of the ground; they are generally free of inclusions, and have high uniform clarity.
This issue appeared as a front-page story in The Wall Street Journal on 29 August 1984 in an article by Bill Richards, Carats and Schticks: Sapphire Marketer Upsets The Gem Industry.
This process was originally developed and patented by Linde Air division of Union Carbide and involved diffusing titanium into synthetic sapphire to even out the blue color.
[6] According to United States Federal Trade Commission guidelines, disclosure is required of any mode of enhancement that has a significant effect on the gem's value.
Heat-treatment in a reducing or oxidizing atmosphere (but without the use of any other added impurities) is commonly used to improve the color of sapphires, and this process is sometimes known as "heating only" in the gem trade.
In contrast, however, heat treatment combined with the deliberate addition of certain specific impurities (e.g. beryllium, titanium, iron, chromium or nickel, which are absorbed into the crystal structure of the sapphire) is also commonly performed, and this process can be known as "diffusion" in the gem trade.
[47] In the flame-fusion (Verneuil process), fine alumina powder is added to an oxyhydrogen flame, and this is directed downward against a ceramic pedestal.
[51] In this process, a tiny sapphire seed crystal is dipped into a crucible made of the precious metal iridium or molybdenum,[52] containing molten alumina, and then slowly withdrawn upward at a rate of 1 to 100 mm per hour.
[53] Synthetic sapphire is also produced industrially from agglomerated aluminum oxide, sintered and fused (such as by hot isostatic pressing) in an inert atmosphere, yielding a transparent but slightly porous polycrystalline product.
Apple contracted GT Advanced Technologies, Inc. to manufacture sapphire screens for iPhones, but the venture failed, causing the bankruptcy of GTAT.
[64] Sapphire is used for end windows on some high-powered laser tubes, as its wide-band transparency and thermal conductivity allow it to handle very high power densities in the infrared and UV spectrum without degrading due to heating.
CMOS chips on sapphire are especially useful for high-power radio-frequency (RF) applications such as those found in cellular telephones, public-safety band radios, and satellite communication systems.
"SOS" also allows for the monolithic integration of both digital and analog circuitry all on one IC chip, and the construction of extremely low power circuits.
In one process, after single crystal sapphire boules are grown, they are core-drilled into cylindrical rods, and wafers are then sliced from these cores.
[citation needed] Wafers of single-crystal sapphire are also used in the semiconductor industry as substrates for the growth of devices based on gallium nitride (GaN).
Titanium-sapphire lasers are popular due to their relatively rare capacity to be tuned to various wavelengths in the red and near-infrared region of the electromagnetic spectrum.