The second government of Ximo Puig was formed on 17 June 2019, following the latter's election as President of the Valencian Government by the Corts Valencianes on 13 June and his swearing-in on 15 June, as a result of the Socialist Party of the Valencian Country (PSPV–PSOE) emerging as the largest parliamentary force at the 2019 regional election.

The cabinet comprised members of the PSPV–PSOE, the Commitment Coalition (Compromís)—with the involvement of Valencian People's Initiative (IdPV) and Valencian Nationalist Bloc (Bloc, later transformed into More–Commitment)—and United We Can (Unides Podem)—comprising We Can (Podem) and United Left of the Valencian Country (EUPV)—, as well as a number of independents proposed by the first party.

[3][4] It was automatically dismissed on 29 May 2023 as a consequence of the 2023 regional election, but remained in acting capacity until the next government was sworn in.

Puig's second government saw a number of cabinet changes during its tenure: The Council of Government was structured into the offices for the president, the two vice presidents, 11 ministries and the posts of secretary and spokesperson of the Council.

[18] Ximo Puig's second government was organised into several superior and governing units, whose number, powers and hierarchical structure varied depending on the ministerial department.