On 12 February, Tina Maze won the women's downhill, becoming the first ever Winter Olympic gold medalist for Slovenia.

Peter Prevc and Žan Košir each won one silver and one bronze medal in ski jumping and snowboarding, respectively.

[3] Tomaž Razingar, the captain of the ice hockey team, was chosen as the flag bearer at the opening ceremony.

Pre-games favourites included alpine skier Tina Maze, a double silver medallist from Vancouver, who won the 2013 Alpine Skiing World Cup with a huge margin and victories in all five disciplines in a single season, biathlete Jakov Fak, bronze medallist from Vancouver where he represented Croatia, snowboarder Rok Marguč, the 2013 World Champion in parallel slalom,[10][11] and the Slovenian ski jumping team, together with Peter Prevc (2nd in the World Cup standings prior to the Olympics) at both individual events.

[12] Petra Majdič, who won bronze in Vancouver in cross-country skiing, concluded her competitive career in 2011 and came to Sochi as the leader of Slovenian delegation.

[14] Snowboarder Cilka Sadar suffered a knee injury at halfpipe training which also caused her withdrawal from the competition.

[15] Matija Mihič, who qualified for snowboard cross, suffered a knee injury before coming to Sochi and did not travel to Russia.

Following a 4th place in combined, Tina Maze won the gold medal in downhill on 12 February, tying with Dominique Gisin of Switzerland.

[19] Other Slovenian skiers were moderately successful, with Maruša Ferk and Ilka Štuhec finishing 10th in combined and downhill, respectively.

Slovenia did not compete in the mixed relay since Andreja Mali failed to qualify for the Olympics individually.

[27] After the race, the Slovenian and Canadian teams filed a complaint to FIS, pointing out presumed irregularities in the equipment of French competitors.

[36][37] In Nordic combined, Slovenia's best result was a 16th place of Marjan Jelenko at large hill/10 km event.

Peter Prevc came to Sochi as 2nd-ranked in the World Cup standings and Slovenia won both team events of the season.

[39] Prevc was third after the first round and gained another place in the finals, winning a silver medal and finishing just after Kamil Stoch of Poland.

Prevc was fourth after the first round and again gained one place in the finals, winning his second Olympic medal, a bronze.

[41] In the inaugural women's normal hill event, Maja Vtič finished 6th after a weaker landing in the first series.

In the third place race, Košir defeated Patrick Bussler of Germany, thus winning bronze, the first medal for Slovenian snowboarders.

In parallel slalom, Košir made it to the finals, where he won his second Olympic medal, a silver, coming second to Vic Wild of Russia.