[2][3] Molan attended high school at Ballarat's Loreto College where she was best on ground in a Herald Sun Shield Intermediate premiership victory in 2017.

[4][5] Molan played representative football at NAB League level with the Greater Western Victoria Rebels, and captained the side in her draft year in 2019.

[8][9][10] She made her debut at VFL Women's level that same year, playing a total of six matches with the Rebels-aligned Western Bulldogs including a losing grand final.

[13] Molan made her debut in the club's inaugural match, a round 1 home game against Carlton at Ikon Park.

[14] Molan plays as a tall ball-winning inside midfielder and is adept at handballing clear of stoppage situations.