Vulović resigned as mayor of Zubin Potok in November 2022, amid the backdrop of a Serb List boycott of the Republic of Kosovo's political institutions.
[4][5] Vulović received the fourth position on a coalition electoral list led by the Socialist Party of Serbia (SPS) for the Kosovska Mitrovica division in the 1997 Serbian parliamentary election.
[10] Vulović appeared in the twenty-eighth position on the Socialist Party's mostly alphabetical list in the 2000 Serbian parliamentary election, which was held in December of that year.
Vulović was identified in a December 2000 news report as chair of the Zubin Potok municipal assembly, a position that was at the time equivalent to mayor.
In this capacity, he helped to facilitate the distribution of voting materials to Kosovo Serb communities in the 2000 parliamentary election.
[16][17] He also ran as the candidate of the Serb List in the subsequent mayoral by-election; describing the vote as "a referendum on how much the state of Serbia will be present here," he called for a high turnout.
Shortly after his election, Vulović criticized the Kosovo Police for making an incursion into Zubin Potok under the auspices of anti-smuggling campaign.
He contended that the people arrested had no connections to the underground economy and that the police had causes significant property damage through their actions.