[2][3] Italy's Lorenzo Vismara finished fourth in 22.11, while Poland's Bartosz Kizierowski was a fraction behind the leading pack in sixth at 22.22.
Russia's double defending champion Alexander Popov finished outside the medals in sixth place with a time of 22.24.
[2] Earlier in the prelims, Volynets made a surprise packet with a ninth fastest time and a Ukrainian record of 22.52 to lead the sixth heat.
[5] Ervin stopped swimming competitively in 2003, auctioned off his gold medal on eBay to aid survivors of the 2004 tsunami, but returned from retirement to claim his place on his second Olympics, in London, twelve years after his first.
[6][7][8] Both men would later continue to win another gold in this event outright (Hall, Jr. in 2004 and Ervin in 2016), edging out the runner-up by 0.01 second in their respective races.