Born in Buenos Aires, De Vincenti was spotted by PAS Giannina scouting team during his youth career with CA Excursionistas, resulting in his first ever professional contract, with a duration of four years.

[8] On 11 May 2014, De Vincenti scored the first hat-trick of his career in APOEL's 8–1 home triumph over Anorthosis for the Cypriot First Division play-offs, netting three goals in the first 32 minutes of the match.

[11][12] Ten days later, De Vincenti won also the Cypriot First Division after APOEL's 1–0 away victory against AEL Limassol in the title deciding match of the competition.

[16] On 30 July 2014, he scored APOEL's first goal and created the second one, in his team's 2–2 first leg draw against HJK Helsinki at Sonera Stadium for the third qualifying round of the UEFA Champions League.

[17] One week later, he scored again against HJK Helsinki, converting a penalty he won himself and helping APOEL to qualify for the play-off round of the 2014–15 UEFA Champions League after a 2–0 home victory.

[22][23] On 24 May 2015, De Vincenti scored the opening goal in APOEL's 4–2 victory over Ermis Aradippou and celebrated the double, as his team secured their third consecutive championship title.

[29] On 11 August 2016, De Vincenti joined the UAE Arabian Gulf League side Al Shabab on a three-year contract, after completing his transfer from APOEL for a reported fee of €3 million.