Triphenylmethyl radical

[4] When exposed to air, the radical rapidly oxidizes to the peroxide, and the color of the solution changes from yellow to colorless.

[5] Other derivatives of the triphenyl radical with certain substituted phenyl groups do form dimers with a hexaphenylethane-like structure.

Theoretical calculations on a very high level of theory indicate that van der Waals attraction between the tert-butyl groups create a potential minimum that is absent in the unsubstituted molecule.

[6][7] Other derivatives have been reported as the quinoid dimer [8] The class of triaryl-methyl radicals have applications in the synthesis of organic magnets.

[10][11][12] He tried to prepare hexaphenylethane from triphenylmethyl chloride and zinc in benzene in a Wurtz reaction and found that the product, based on its behaviour towards iodine and oxygen, was far more reactive than anticipated.

Kekulé, skeletal formula of the triphenylmethyl radical
Kekulé, skeletal formula of the triphenylmethyl radical
Ball-and-stick model of the triphenylmethyl radical
Triphenylmethyl radical
Triphenylmethyl radical
Triphenylmethyl radical oxidation
Triphenylmethyl radical oxidation