Ukraine competed at the 2000 Summer Olympics in Sydney, Australia.

230 competitors, 139 men and 91 women, took part in 185 events in 23 sports.

[1] The silver medal that the Ukrainian women's team won in Sydney was the best result the Ukrainian archery squad had yet posted.

Qualification Legend: 'R = Qualify to repechage; QS = Qualify to semi-final; QF = Qualify directly to final Time Time Time Ten fencers, seven men and three women, represented Ukraine in 2000.

M = Medal race; EL = Eliminated – did not advance into the medal race; CAN = Race cancelled Six Ukrainian shooters (four men and two women) qualified to compete in the following events: Ukraine nominated two female tennis players to compete in the tournament.