Ukraine is a nation that has competed at the Hopman Cup tournament on four occasions, the first being in 1993.

In 1995 and 2016, Ukraine were the tournament runners-up and this remains their best showing to date.

[1] Before its dissolution, Ukraine used to form part of the Soviet Union which also competed at the Hopman Cup on two occasions in the early 1990s.

1 As Andrei Medvedev and Natalia Medvedeva had already lost both of their singles matches, the mixed doubles dead rubber was not played.

2 In the final against Germany, the mixed doubles dead rubber was not played as Andrei Medvedev and Natalia Medvedeva had already lost both of their singles matches.