The title given by the United States State Department to this position is currently Ambassador Extraordinary and Minister Plenipotentiary.

The following were commissioned either Chargés d'Affaires or Ministers to Gran Colombia.

The following were commissioned as either Chargés d'Affaires or Ministers to New Granada.

The following were commissioned as Ministers to the United States of Colombia.

The following were commissioned as either Ministers or Ambassadors to the Republic of Colombia.