March 26, 2006 – firstly elected as People's Deputy of the Verkhovna Rada of Ukraine for Bloc Yulia Tymoshenko.

[1] November 23, 2007 – elected as People's Deputy of the Verkhovna Rada of Ukraine of the 6th convocation again for Bloc Yulia Tymoshenko:[1] In 2009 Pysarenko became a member of the parliamentary faction of the Party of Regions.

[1] During parliamentary elections on December 12, 2012 won single-mandate constituencies No.168, Kharkiv city as an independent candidate:[1] October 26, 2014 – elected as People's Deputy of the Verkhovna Rada of Ukraine of the 8th convocation on majority constituency No.168, Kharkiv again as an independent candidate:[1] In 2015 Pysarenko became a member of the parliamentary faction of the party Revival.

[1] In the 2019 Ukrainian parliamentary election Pysarenko failed to get reelected after finishing second in majority constituency No.168 (Kharkiv) (again as an independent candidate) with 24.38% after Maria Mezentseva of Servant of the People with 41.51%.

[4][5] January 2016 – Valeriy Pysarenko participated in the World Future Energy Summit in Abu Dhabi, UAE.

November 2016 – Valeriy Pysarenko initiated conduction of IX International Forum "Energy for Sustainable Development" in Ukraine in 2018 ".

The exhibition was held in the framework of the 25th session of the Committee on Sustainable Energy of the United Nations Economic Commission for Europe.

[11]The exhibition consists of two photo projects of Ukrainian artists "When sin is not clear, there is no fault more ..." by Yurii Kosin and "Prypyat Mon Amour" by Alina Rudia.

Wearing VR-glasses, you can go for an interactive journey and see the new Confinement at Chernobyl – an enormous engineering construction higher than Wembley stadium, you can walk on the abandoned school, amusement park and other objects in Pripyat.

March 28 – April 12, 2017 – Valeriy Pysarenko as a part of in the Ukrainian delegation represented Ukraine in Beijing (China) in International Seminar "Energy Strategy for the Belt and Road Countries".

In 2016 the NGO "New Frontiers" first in Kharkiv started work on enforcing of Sustainable Development Goals, approved by the United Nations into youth lives.

In December 2016 "New Frontiers" began working on an educational project of the United Nations, as part of Sustainable Development Goals, "The World's Largest Lesson".