Vezović was born in Belgrade, PR Serbia, Yugoslavia.

In 1962, he started to play basketball and grew up with Crvena Zvezda youth teams.

[1] Vezović was a head coach for the Nigeria women's national team that won the bronze medal at the 1978 All-Africa Games in Algeria.

He also coached teams in Greece (Apollon Patras, Iraklio, Maroussi, and Ilysiakos), Cyprus (ENAD Nicosia and Olimpiada Nicosia), Qatar (Al Rayyan), and Poland (MKS Pruszków).

[1] Pound sign (#) denotes interim head coach.