Volče (pronounced [ˈʋoːu̯tʃɛ]; Italian: Volzana) is a settlement on the right bank of the Soča River in the Municipality of Tolmin in the Littoral region of northwestern Slovenia, close to the border with Italy.

[2] Volče was attested in historical sources as Volzana in 1295, Olza in 1338, Walçana in 1340, and Volzane in 1341.

The name is derived from the plural demonym *Volčane based on the given name *Vьlkъ, thus originally meaning 'Volk's people' or 'residents of Volk's village'.

[3] The parish church in the settlement is dedicated to Saint Leonard and belongs to the Koper Diocese.

A second church, built outside the settlement, is dedicated to the Prophet Daniel.