His father had managed to secure the independence from the Byzantine Empire after the death of emperor Manuel I (1180), and then conquered the traditional fiefs of Duklja, Travunija and Hum on the Adriatic coast.
Nemanja gave Vukan, as heir apparent, appanages of the conquered lands, including Hvosno and Toplica around 1190 as grand prince.
[1] In an inscription dated 1195 in the church of St. Luke in Kotor, Vukan is titled as King of Duklja, Dalmatia, Travunia, Toplica and Hvosno.
It seems that Vukan reacted on this change in succession by declaring himself King of Duklja in 1195 probably due to the relationship of his family with old Dukljan royal house which was deposed by his father.
On intervention of the third brother, archbishop Sava, Stefan spared Vukan and return him to his apanage in Zeta (Duklja) where he kept his title of king.