His father began his political career as a Foreign Minister to the Russian Tsar Alexander I after Poland was partitioned by Russia, Prussia and Austria.

In 1878, he reopened the Czartoryski Museum in Kraków, founded by his grandmother Izabela Czartoryska in 1801 in Puławy but closed after the November Uprising.

[4] Władysław hoped that his eldest son would pursue a diplomatic career, however, Gucio went against his father's wishes and joined the religious order of the Salesians.

She was a daughter of Queen Maria Christina of Spain by her morganatic second marriage to Agustín Fernando Muñoz, Duke of Riánsares.

[5] Before her death from tuberculosis in 1864, they were the parents of: On 15 January 1872 Prince Władysław married his second wife, Princess Marguerite Adelaide of Orléans, daughter of the Duke of Nemours and granddaughter of King Louis-Philippe of France, with whom he had two more sons:[5] He died on 23 June 1894 in Boulogne-sur-Seine and was buried in the Sieniawa family crypt.