The race began in Salou with a team time trial and ended in Barcelona.

The race was won by Russian Vladimir Karpets of the Caisse d'Epargne team, who won the race thanks to winning the team time trial, and second placings on the toughest mountain stage (stage 4) and the mountain time trial (stage 5).

The race also saw the first UCI ProTour victories for young British sprinter Mark Cavendish of the T-Mobile Team, when he took stages 2 and 6.

Twenty-five teams of up to eight riders started the race:[1] 21 May 2007: Salou to Salou, 15.7 km (9.8 mi) (TTT)[4] 22 May 2007: Salou to Perafort, 170 km (110 mi)[5] 23 May 2007: Perafort to Tàrrega, 182.1 km (113.2 mi)[6] 24 May 2007: Tàrrega to Vallnord-Arinsal (Andorra), 201.1 km (125.0 mi)[7] 25 May 2007: Sornas to Vallnord-Arcalís (Andorra), 17.1 km (10.6 mi) (ITT)[8] 26 May 2007: Llívia to Lloret de Mar, 177.1 km (110.0 mi)[9] 27 May 2007: Lloret de Mar to Barcelona, 119.3 km (74.1 mi)[10]

As of 27 May 2007, after the Volta a Catalunya [11] While the top 10 places remain the same, race winner Vladimir Karpets moves into 13th position.