Although Mario Galinović was considered the first option for the goalkeeper position for the 2008–2009 season, Tzorvas had his chances already in October being in the starting eleven for a few games for the Greek Superleague and the UEFA Champions League.

For the 2009–10 Super League season, beginning from the match against Aris Thessaloniki F.C., he is considered a basic choice for the goalkeeper position, mainly due to bad performances by teammate Galinović.

Originally hired as starting goalkeeper, he fell out of favour with head coach Devis Mangia following some unimpressive performances and ultimately lost his place to Francesco Benussi.

The former Panathinaikos shot-stopper was mentioned in a report released by La Gazzetta dello Sport as Udinese looks to fill the void between the sticks following the sale of Samir Handanovic to Inter Milan and the nerve-racking injury to expected starter Zeljko Brkic.

With Udinese set to compete in the play-off round of the UEFA Champions League, the Northeastern Italian club provides an attractive destination for Tzorvas despite the departure of many key players this season.

His first game with the club was a catastrophe, as he smothered a Stevan Jovetić snapshot, but David Pizarro hit a fierce effort that took a massive deflection to loop over the goalkeeper and land on the crossbar.

Greece international Alexandros Tzorvas has agreed to join newly promoted Greek Super League side Apollon Smyrni on a two-year deal, the club has confirmed.

After a decent spell at NorthEast United FC, the Greek press reported in March 2015 that Tzorvas was considering a return to India as he has been approached by two unidentified Indian clubs with significant offers.

Tzorvas turned away the Ukrainian attack for the entire 180 minutes over ties in Athens and Donetsk, sustaining the Greeks' 1–0 aggregate victory that sent the team to the 2010 FIFA World Cup in South Africa.