After winning her first title in 2008, Dobromyslova decided to join the rival male-dominated Professional Darts Corporation (PDC) to play in their World Championship in 2009.

[2] She made her professional major debut at the 2004 Bavaria World Darts Trophy, where she beat Trina Gulliver in the quarter-final, averaging 90.

In October, she represented Russia in the 2007 WDF World Cup in the Netherlands, and won the ladies' pairs title with Irina Armstrong.

[3] In the first round, she was drawn to play Robert Thornton, who was also a BDO player who won through the Pub Qualifiers, and was the reigning World Masters champion.

[2] She was named the number one seed for the 2008 Zuiderduin Masters, but was excluded from playing by the Dutch authorities after problems with her visa, and was forced to withdraw.

In her group, she was drawn with reigning PDC world champion John Part, Kevin McDine, and Wayne Mardle.

[2] In December, she went into the 2008 World Masters as the number one ranked ladies' darts player, and reached the final, where she lost to Hoenselaar.

[2] Following their failed takeover bid of the BDO, the PDC introduced their own Women's World Championship, and Dobromyslova automatically qualified as the only female member of the PDPA.

[2] At the 2009 Grand Slam of Darts, Dobromyslova was drawn with Phil Taylor, Vincent van der Voort, and Mark Webster.

PDC awarded his preliminary round place to the runner-up of the PDPA qualifying event (which later turned out to be Matt Padgett), rather than Dobromyslova.

[2] On 24 December 2010, it was rumoured amongst several darts internet forums that Dobromyslova had resigned from the PDC and returned to play in BDO and WDF events.

[6] She qualified for the 2012 BDO World Darts Championship, where in the quarter-final, she defeated second seeded Welsh woman Julie Gore by two sets to nil.

[13] [2] [2] [2] [2] [2] [2] Dobromyslova is married to Tony Martin, who qualified for the 2005 BDO World Darts Championship and resides in Ellesmere Port, Cheshire, England.