Dmytriv was born in Ukraine, and moved to Spain, with her parents at two years old.

[1] Dmytriv made her international debut for Spain at the 2022 World Para Swimming Championships and won a gold medal in the 100 metre breaststroke SB8, a silver medal in the mixed 4 × 100 m medley relay 34pts and a bronze medal in the 200 metre individual medley SM9 events.

[2][3] Dmytriv represented Spain at the 2024 Summer Paralympics and won a gold medal in the 100 metre breaststroke Sb8 event[4] and a bronze medal in the Mixed 4×100 m medley relay-34pts category.

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