The Junkie XL remix of "And Then We Kiss" is a Eurotrance song with influences of techno and usage of dance-rock guitars, synthesizers and symphonic strings.

The Junkie XL remix of "And Then We Kiss" was well received by music critics, with some noticing its potential to be a radio or club hit.

The song failed to appear on any major record charts, however, it peaked at number 15 on the US Billboard Hot Dance Airplay.

This version produced by Taylor features an electronica vibe reminiscent of Madonna's Ray of Light (1998), and contains a flamenco guitar with prominent lead vocals by Spears.

[2] "And Then We Kiss" was set to be included as a UK and Japan bonus track on Britney & Kevin: Chaotic (2005), but was replaced with "Over to You Now" for unknown reasons.

[4] In September 2005, it was announced by Billboard that the remix would serve as the music for the ad campaign behind Spears' fragrance, Fantasy.

[2] In an interview with About.com, Junkie XL said he wanted to turn the song "into a 2006 version of Enjoy the Silence with really electronic chunky beats and nice melodic guitar lines.

Jennifer Vineyard of MTV noted "And Then We Kiss" had "the potential to be a radio or club hit — if Jive were actively promoting [B in the Mix]".

"[15] "And Then We Kiss" was not officially released as promotional single in the United States, therefore it was not eligible at the time to appear on Billboard's Hot 100.