Poyos first appeared with the UST Golden Tigresses in the 2023 Shakey's Super League National Invitationals, where they earned a bronze medal.
[2][3] Poyos made her UAAP debut with the UST Golden Tigresses in Season 86, immediately making impressions as she scored 31 points in one match, setting a new scoring record for a first-year player in the history of UAAP Women's Volleyball.
[4][5][6] On May 12, 2024, the UST Golden Tigresses reached the finals and faced the NU Lady Bulldogs, where Poyos sustained a sprained ankle during the second set and was absent for the rest of Game 1.
[7] On May 15, she was cleared to return for Game 2 but was pulled out halfway through the first set due to her injury affecting her performance.
[8] The UST Golden Tigresses earned the silver medal, while Poyos received the Rookie of the Year award and was recognized as the second-best Outside Hitter, as well as being the second highest scorer in the entire tournament.