Atmospheric chemistry

This multidisciplinary approach of research draws on environmental chemistry, physics, meteorology, computer modeling, oceanography, geology and volcanology, climatology and other disciplines to understand both natural and human-induced changes in atmospheric composition.

Besides the major components listed above, the Earth's atmosphere contains many trace gas species that vary significantly depending on nearby sources and sinks.

These trace gasses include compounds such as CFCs/HCFCs which are particularly damaging to the ozone layer, and H2S which has a characteristic foul odor of rotten eggs and can be smelt in concentrations as low as 0.47 ppb.

Further studies on ozone issues led to the 1995 Nobel Prize in Chemistry award shared between Paul Crutzen, Mario Molina and Frank Sherwood Rowland.

The changing climate and the recovery of the ozone hole and the interaction of the composition of the atmosphere with the oceans and terrestrial ecosystems are examples of the interdependent relationships between Earth's systems.

Astrochemists analyze the atmospheric compositions of our solar system and exoplanets to determine the formation of astronomical objects and find habitual conditions for Earth-like life.

Observatories such as the Mauna Loa and mobile platforms such as aircraft ships and balloons (e.g. the UK's Facility for Airborne Atmospheric Measurements) study chemical compositions and weather dynamics.

Observations of atmospheric composition are increasingly made by satellites by passive and active remote sensing with important instruments such as GOME and MOPITT giving a global picture of air pollution and chemistry.

Experiments are performed in controlled environments, such as aerosol chambers, that allow for the individual evaluation of specific chemical reactions or the assessment of properties of a particular atmospheric constituent.

[15] A closely related subdiscipline is atmospheric photochemistry, which quantifies the rate that molecules are split apart by sunlight, determines the resulting products, and obtains thermodynamic data such as Henry's law coefficients.

Commonly used instruments to measure aerosols include ambient and particulate air samplers, scanning mobility particle sizers, and mass spectrometers.

For example, box modeling is relatively simple and may include hundreds or even thousands of chemical reactions, but they typically use a very crude representation of atmospheric mixed layer.

This approach has gained attention over the past decade as an effective method to interpret large amounts of data generate by models and observations from satellites.

Atmospheric chemistry is a multidisciplinary field with wide-ranging applications that influence environmental policy, human health, technology development, and climate science.

Examples of problems addressed in atmospheric chemistry include acid rain, ozone depletion, photochemical smog, greenhouse gasses and global warming.

Atmospheric chemistry also helps quantify the concentration and persistence of toxic substances in the air, including particulate matter and volatile organic compounds (VOCs), guiding public health measures and exposures assessments.

Visualisation of composition by volume of Earth's atmosphere. Water vapour is not included as it is highly variable. Each tiny cube (such as the one representing krypton) has one millionth of the volume of the entire block. Data is from NASA Langley .
The composition of common nitrogen oxides in dry air vs. temperature
Chemical composition of atmosphere according to altitude . [ 1 ] Axis: Altitude (km), Content of volume (%).
Schematic of chemical and transport processes related to atmospheric composition
Three boxes stacked on top of one another with vertical arrows to show elevation and horizontal arrows to show transportation. Aerosols enter the box via human, plant, and wind transport and exit via dry or wet deposition.
Schematic of a one-dimensional column model depicting the movement and transformation of aerosols. [ 17 ]