[6] It was first mentioned by Philip Rashleigh in 1797 as an ore of antimony and was more completely described in 1804 by French crystallographer and mineralogist Jacques Louis, Comte de Bournon (1751–1825), after whom it was named.

[6] They are usually twinned, the twin-plane being a face of the prism (m); the angle between the faces of this prism being nearly a right angle (86° 20′), the twinning gives rise to cruciform groups and when it is often repeated the group has the appearance of a cog-wheel, hence the name Rãdelerz (wheel-ore) of the Kapnik miners.

It commonly occurs with galena, tetrahedrite, sphalerite, chalcopyrite, pyrite, stibnite, zinkenite, siderite, quartz, rhodochrosite, dolomite and barite.

[2] It was first described for an occurrence in Wheal Boys in the parish of St Endellion in Cornwall,[7] it was found associated with jamesonite, sphalerite and siderite.

Fine crystals of large size have been found with quartz and siderite in the mines at Neudorf in the Harz, and with sphalerite and tetrahedrite at Cavnic near Baia Mare in Romania.