Caledonia entered Lloyd's Register for 1805 with Hamilton, master, Geddies (or Geddes), owner, and trade Liverpool–Africa.

1st voyage transporting enslaved people (1805–1806): Captain Hamilton sailed from London on 16 October 1805, bound for West Central Africa and Saint Helena.

[5] 2nd voyage transporting enslaved people (1807–1808): Captain William Miller acquired a letter of marque on 20 May 1807.

Between 1 January 1806 and 1 May 1807, 185 vessels cleared Liverpool, bound for Africa and the transport of captives to the West Indies.

[7] Lloyd's List for 28 March 1809 reported that Caledonia, Miller, master, had arrived at Gothenburg.

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