Duhaime played third for Ontario at the 2008 Canadian Junior Curling Championships on a team skipped by Danielle Inglis.
She skipped the Fanshawe College Falcons at the 2012 CCAA Curling Invitational Championship, winning the gold medal.
After her college career, Duhaime continued to skip her own team on the Ontario and World Curling Tours.
In their first season together, the team won the CookstownCash presented by Comco Canada Inc. and the Stroud Sleeman Cash Spiel.
In the 2017-18 curling season, Duhaime qualified for her first Grand Slam event, the 2017 GSOC Tour Challenge, where the team would lose in a tiebreaker.