On C: and This is the first of the six hexachords identified by Milton Babbitt as all-combinatorial source sets, a "source set" being "a set considered only in terms of the content of its hexachords, and whose combinatorial characteristics are independent of the ordering imposed on this content" (Babbitt 1955, 57).
As with the diatonic scale, the chromatic hexachord is, "hierarchical in interval makeup," and may also be produced by, or contains, 3-1, 3-2, 3-3, 3-6, and 3-7 (Friedmann 1990, 111).
Serial compositions including Karlheinz Stockhausen's Kreuzspiel and Klavierstück I feature the chromatic hexachord in permuted orderings, as do certain pieces composed by Milton Babbitt, Alban Berg, Ernst Krenek, Luigi Nono, Karlheinz Stockhausen, Igor Stravinsky, and Anton Webern in various fixed-order derivations (twelve-tone rows and arrays).
The retrograde-symmetrical all-interval series employed by Luigi Nono for the first time in Canti per tredeci in 1955, also used in his Il canto sospeso and nearly all subsequent works up to Composizione per orchestra n. 2: Diario polacco ’58 in 1959, is built from two chromatic hexachords (Nielinger 2006, 97–98).
Stefan Wolpe's Suite in Hexachord (1936) begins with a chromatic hexachord on G, introducing the complementary hexachord in the final movement, while Elliott Carter calls his own piece, "Inner Song" for solo oboe—the second movement of Trilogy for oboe and harp (1992)—"some thoughts about Wolpe's hexachord" (Schiff 1998, 146).