[2] He later returned to San Bartolomé this time as a professor in the areas of Algebra, Mathematics, Trigonometry, Philosophy[3] Metaphysics, and Ethics.

[9] On September 23, 1814, the Neogranadine Congress, modified the Federal Act relating to the seat of power, and replaced the Presidency with a Triumvirate,[10] a three-member executive body, to rule over the country.

It is not sure whether they knew each other from before, but on the way to Popayán, Pepita, of only 16 years of age, caught the attention of Custodio, and María Josefa asked to take her with him, as she would prefer to face the dangers of the jungle than to be captured by the Spaniards,[17] their mutual affection escalated, and Custodio asked María Josefa to marry her.

And so, in the mist of war, in an improvised ceremony, they got married by Friar Francisco Antonio Florido, who was also fleeing Bogotá with them.

[18] Short after Liborio Mejía was vested with the presidential powers, he led his small army to face Juan Sámano in the Battle of Cuchilla del Tambo which culminated with the defeat of the patriots on June 29.

A great effort was made to fight the Spaniards, but they were defeated on July 10, and those who managed to escape, including García, were captured a few days later.

After the defeat of the Spaniards years later, Santander granted pension to the widows of the martyrs of the Independence, among them Piedrahita de García.