He was part of the Williams family of painters, who were related to such famous artists as James Ward RA and George Morland.
He adopted much of his father's style and technique, and like the other painters of his family, he devoted himself to landscapes, producing rich and tranquil views of Barnes, Cumberland, Kent, Surrey and the Thames.
He largely stopped painting after the 1859 death of his second wife, adding value to the small number of paintings that he did produce from 1859 on − Springer in the Bracken, The Lap Dog, The Ploughman's walk home, The Ducks at Tilbury and Primrose at St Mary's (Primrose was the Verger's Cat).
Mary Ann died in 1857 in London, and his only child Alice Williams was born shortly afterwards to Sarah Susannah Horley, who had been Mary Ann's nurse – Edward and Sarah did not marry for another 10 years until 3 October 3, 1868, when they wed at the St. Pancras Old Church in Camden, London.
[5] He died 25 July 1881 at Shepherd's Bush in London and is buried with Sarah Horley and their daughter Alice in Hammersmith Old Cemetery, close to other family graves.